固定化海藻对金属离子吸附效果的研究   总被引：4，自引：0，他引：4  

王宪  钱爱红  邱海源  郑盛华  陈丽丹 《海洋学报》2005,27(5):126-130

研究了固定化海带吸附含铜、镉溶液的过程,结果表明:非活性海带吸附水溶液中铜、镉离子的动力学过程可以用班厄姆吸附速率方程描述,铜和镉的吸附速率常数分别为0.1078和0.03028min-1;生物吸附过程符合Langmuir模型,根据Langmuir吸附等温模型的计算结果,得到固定化海带对铜和镉离子的最大吸附量分别为83.3和112.4mg/g,海带对铜离子的亲和性比对镉离子强.  相似文献   

Morphodynamics and cobbles behavior in and near the surf zone     

S. I. Voropayev  F. Y. Testik  H. J. S. Fernando  D. L. Boyer 《Ocean Engineering》2003,30(14):1741-1764

The evolution of an initially flat sandy slope and the dynamics of large objects (cobbles/mines) emplaced on it are studied in a laboratory wave tank under simulated surf conditions. Upon initiation of wave forcing, the initially flat beach undergoes bedform changes before reaching a quasi-steady morphology characterized by a system of sand ripples along the slope and a large bar near the break point. Although the incoming wave characteristics are held fixed, the bottom morphology never reaches a strict steady state, but rather slowly changes due to the migration of ripples and bar transformation. When the wave characteristics are changed, the bedform adjusts to a new quasi-steady state after a suitable adjustment time. Studies conducted by placing model cobbles/mines on the evolving sandy bottom subjected to wave forcing show four distinct scenarios: (i) periodic cobble oscillations with zero mean displacement and small scour around the cobbles, (ii) mean onshore motion of relatively light cobbles, (iii) periodic burial of relatively heavy cobbles when their sizes are comparable to those of sand ripples, and (iv) the burial of relatively large cobbles under the bar, when the bar migrates due to changes of incoming waves. Quantitative data on the characteristics and dynamics of the bedform, including ripple-formation front propagating down the slope, ripple growth and drift, and flow around ripples, are presented. Physical explanations are provided for the observations.  相似文献   

地衣芽孢杆菌胞外产物消化活性的研究   总被引：12，自引：0，他引：12  

曹煜成  李卓佳  冯娟  陈永青  吴灶和 《热带海洋学报》2005,24(6):6-12

将地衣芽孢杆菌Bacillus licheniformis的胞外产物置于不同的pH、温度和金属离子条件下,分别测定其蛋白酶、淀粉酶、脂肪酶活性的变化。结果表明,当pH为7.5—8.5时胞外产物表现出较高的蛋白酶和淀粉酶活性,胞外产物消化脂肪的最适pH为9.0—10.0。胞外产物水解淀粉、脂肪和蛋白质最适温度分别为60—80、40—60和50—70℃,60℃时蛋白酶活力最大。试验测定了8种金属离子对胞外产物活性的影响,发现Mg2+、Zn2+Cu2+可抑制其水解蛋白质,而Ca2+、Fe3+、Mn2+和Ba2+却无此影响;在胞外产物消化脂肪底物时Co2+、Fe3+、Mn2+和Ba2+均能抑制其活力,而Mg2+、Zn2+能使其消化活力升高,与前者相比,金属离子对淀粉水解的影响相对较小,仅Cu2+有一定的抑制作用,其它离子对其均无明显的影响。还研究了不同胞外产物浓度与生物学活性的相关性,发现当反应体系中胞外产物浓度升高时水解蛋白质的活力会相应降低,但对脂肪的消化活力则与胞外产物的浓度呈正相关。反应体系中胞外产物的浓度在0—132.4μg.ml-1时其水解淀粉的活力随浓度的升高而升高,浓度为191.0μg.ml-1时活力最大,浓度大于191.0μg.ml-1时活力不再变化,稳定在一个较高的水平。  相似文献   

福建罗源湾网箱养殖区海洋生态环境质量评价   总被引：1，自引：0，他引：1  

蔡清海  杜琦  钱小明  许翠娅 《海洋科学进展》2007,25(1):101-110

对比2004年的调查资料与历史资料,分析了罗源湾海区多年水质、水域的养殖力(营养盐、叶绿素a和初级生产力)以及浮游植物多样性的变化,并采用潜在生态危害指数法对其生态危害程度现状进行评价。结果表明,罗源湾水体中的无机氮和活性磷酸盐质量浓度超过第二类水质标准,沉积物中除Hg、Cd污染较为严重外,其它重金属的生态危害很小。此外,罗源湾表层沉积物微量元素含量属正常范围。目前,罗源湾网箱养鱼已超负荷,但养殖面积还有扩大趋势,故必须调整网箱养殖面积和数量,优化养殖种类结构,实现生态养殖,才能达到持续健康、高质、高效发展。  相似文献   

重金属污水对木榄幼苗几种保护酶及膜脂质过氧化作用的影响   总被引：23，自引：1，他引：23  

张凤琴  王友绍  董俊德  孙翠慈  殷建平 《热带海洋学报》2006,25(2):66-70

用5个级别的人工复合重金属污水处理红树植物木榄Bruguiera gymnorrhiza幼苗,2个月后对其叶片和根系中的保护酶SOD、POD和CAT活性变化以及对膜脂质过氧化作用的影响进行分析。结果显示,当污染级别不大于5倍污水时,根系中SOD活性随污染程度的增加而增加,污染程度再升级其活性迅速下降但仍高于对照组水平;叶片中SOD活性在1倍污水时与对照组相比有所下降,随后的变化与在根系中的变化相似。POD活性在根系和叶片中的变化相对一致,均随污染级别的增加而升高;但在叶片中的变化幅度大于根系中的变化幅度。CAT活性在叶片中不受污染程度的影响,保持平稳,但在高程度污染下活性有下降趋势;而根系中CAT活性在10倍污水时达到最大值,污染程度再升级其活性下降。叶片中膜脂质过氧化作用随污染程度的增加而加剧,MDA的积累增加;但根系中MDA含量在5倍污水时最少,只为对照组的21.98%,其后随着污染程度的增加其MDA含量大幅度积累,膜脂质过氧化作用加剧。从整个试验结果分析认为,木榄在遭受重金属胁迫时具有优先保护根系以增强植物的抗重金属能力。  相似文献   

Experimental Study of Factors Controlling Sorption of Heavy Metals on Ariake Clay and Implication for Practice     

Y. J. Du  S. Hayashi 《Marine Georesources & Geotechnology》2006,24(2):103-118

A series of batch tests have been presented to investigate the effects of solid-solution contact time, solid:solution ratio, and pH of solution on sorption of Cd²⁺ and Pb²⁺ on Ariake clay from Kyushu region of Japan. The results show that, among the three investigated factors, solid:solution ratio (SD/SN) seems to be the crucial controlling factor. The Freundlich sorption parameters determined from the batch tests were applied to a typical field landfill in which the Ariake clay was used as soil barrier. The impacts of the landfill were assessed by numerical analysis. Based on the analysis result, the significance of selecting proper solid:solution ratio for determining sorption parameters from batch test has been discussed.  相似文献   

Investigation of Cd, Cu, Ni and Th in the colloidal size range in the Gulf of Maine     

Jennifer M. Greenamoyer  S. Bradley Moran   《Marine Chemistry》1997,57(3-4)

Size-fractionated seawater samples were collected from the Gulf of Maine to determine the fraction (f_c/d) of total dissolved (< 1 μm) Cd, Cu, Ni and ²³⁴Th in the colloidal size range (1,000 nominal molecular weight, NMW, to 1 μm) using cross-flow filtration. Colloidal Cd, Cu and Ni represents < 1–7% of the total dissolved concentration in these shelf waters and increases with an increase in particle concentration. By comparison, results obtained for particle-reactive ²³⁴Th indicate that < 1–47% of total dissolved is associated with the colloidal size fraction. A revised relationship between the concentration of colloids (C_c) and suspended particles (C_p) is reported (log C_c = 0.66 log C_p −2.01 kg L⁻¹) and used to examine the dependence of f_c/d for these metals on the concentration of suspended particles for C_p = 0.01–100 mg L⁻¹. Results indicate that a significant fraction (˜ 10–30%) of Cd, Cu, Ni and ²³⁴Th in the traditionally defined ‘dissolved’ fraction may exist in the colloidal size range in regions characterized by high particle concentrations (C_p > 1–10 mg L⁻¹), such as in near-shore and estuarine waters.  相似文献   

开链冠醚2，6-二(8''''-喹啉氧甲基)-4-甲基-苯甲醚及其Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )配合物的合成与性质研究     

张前前  季振平  萧文锦  吴成泰 《中国海洋大学学报(自然科学版)》2001,31(3):420-424

设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚)，经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag(Ⅰ)、Cu(Ⅱ)、Ni(Ⅱ)固体配合物的元素分析结果表明金属离子不同，则其配合物的配位比(M∶L)不同，Ag(Ⅰ)配合物为1∶1，Cu(Ⅱ)、Ni(Ⅱ)配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。  相似文献   

长江口内外悬浮体中Cu,Co的形态变化   总被引：2，自引：0，他引：2  

阮正  王正方 《海洋科学》1990,14(5):25-29

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Fluxes of iron and manganese across the sediment–water interface under various redox conditions     

Svetlana V. Pakhomova  Per O.J. Hall  Mikhail Yu. Kononets  Alexander G. Rozanov  Anders Tengberg  Andrei V. Vershinin 《Marine Chemistry》2007

Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m^− 2 day^− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m^− 2 day^− 1) and high fluxes at suboxic conditions (up to 1000 μmole m^− 2 day^− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r² = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.  相似文献